The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy / neo-C5H11O2,(CH3)3CCH2O2 / DagautKurylo(1990)_298K_210-300nm(meas)

DATAFILE: neo-C5H11O2,(CH3)3CCH2O2_DagautKurylo(1990)_298K_210-300nm(meas).txt
NAME: 2,2-dimethyl-1-propylperoxy radical, neopentylperoxy radical
FORMULA: neo-C5H11O2,(CH3)3CCH2O2
AUTHOR(YEAR): DagautKurylo(1990)
T: 298K
λ: 210-300nm(meas)
BIBLIOGRAPHY: P. Dagaut and M.J. Kurylo, "A flash photolysis investigation of the gas phase UV absorption spectrum and the self-reaction kinetics of the neopentylperoxy radical", Int. J. Chem. Kinet. 22, 1177-1187 (1990); DOI: 10.1002/kin.550221107
COMMENTS: Pulse radiolysis (Cl2/neopentane/O2 mixtures) transient UV absorption spectroscopy

Measured values: Calibration of the relative spectrum to the absolute value
σ(250 nm) = (5.18 ± 0.78)×10-18 cm2 molecule-1

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